Plutonium | Radioactive Element, Nuclear Fuel (2024)

chemical element

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Also known as: Pu

Written by

Lester Morss Adjunct Professor, Department of Chemistry, University of Maryland, College Park, Maryland.

Lester Morss

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Key People:
Glenn T. Seaborg
Cyril Stanley Smith
Harrison Brown
Related Topics:
chemical element
nuclear reactor
plutonium-239
plutonium-238
plutonium-240

See all related content →

plutonium (Pu), radioactive chemical element of the actinoid series of the periodic table, atomic number 94. It is the most important transuranium element because of its use as fuel in certain types of nuclear reactors and as an ingredient in nuclear weapons. Plutonium is a silvery metal that takes on a yellow tarnish in air.

The element was first detected (1941) as the isotope plutonium-238 by American chemists Glenn T. Seaborg, Joseph W. Kennedy, and Arthur C. Wahl, who produced it by deuteron bombardment of uranium-238 in the 152-cm (60-inch) cyclotron at Berkeley, California. The element was named after the then planet Pluto. Traces of plutonium have subsequently been found in uranium ores, where it is not primeval but naturally produced by neutron irradiation.

Britannica QuizFacts You Should Know: The Periodic Table Quiz

All plutonium isotopes are radioactive. The most important is plutonium-239 because it is fissionable, has a relatively long half-life (24,110 years), and can be readily produced in large quantities in breeder reactors by neutron irradiation of plentiful but nonfissile uranium-238. Critical mass (the amount that will spontaneously explode when brought together) must be considered when handling quantities in excess of 300 grams (2/3 lb). The critical mass of plutonium-239 is only about one-third that of uranium-235.

Plutonium and all elements of higher atomic number are radiological poisons because of their high rate of alpha emission and their specific absorption in bone marrow. The maximum amount of plutonium-239 that can be indefinitely maintained in an adult without significant injury is 0.008 microcurie (equal to 0.13 microgram [1 microgram = 10−6 gram]). Longer-lived isotopes plutonium-242 and plutonium-244 are valuable in chemical and metallurgical research. Plutonium-238 is an alpha-emitting isotope that emits a negligible amount of gamma rays; it can be manufactured to harness its heat of radioactive decay to operate thermoelectric and thermionic devices that are small, lightweight, and long-lived (the half-life of plutonium-238 is 87.7 years). The power produced from plutonium-238 alpha decay (approximately 0.5 watt per gram) has been used to provide spacecraft electrical power (radioisotope thermoelectric generators [RTGs]) and to provide heat for batteries in spacecraft, such as in the Curiosity rover.

Plutonium exhibits six forms differing in crystal structure and density (allotropes); the alpha form exists at room temperature. It has the highest electrical resistivity of any metallic element (145 microhm-centimetres). Chemically reactive, it dissolves in acids and can exist in four oxidation states as ions of characteristic colour in aqueous solution: Pu3+, blue-lavender; Pu4+, yellow-brown; PuO2+, pink; PuO22+, yellow or pink-orange; and Pu7+, green. Very many compounds of plutonium have been prepared, often starting from the dioxide (PuO2), the first compound of any synthetic element to be separated in pure form and in weighable amounts (1942).

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Element Properties
atomic number94
stablest isotope244
melting point639.5 °C (1,183.1 °F)
boiling point3,235 °C (5,855 °F)
specific gravity (alpha)19.84 (25 °C)
oxidation states+3, +4, +5, +6
electron configuration of gaseous atomic state[Rn]5f 67s2

Lester Morss

Plutonium | Radioactive Element, Nuclear Fuel (2024)

FAQs

Why is plutonium a nuclear fuel? ›

Some of the neutrons released by uranium interact with other uranium atoms to form plutonium. Some of the plutonium itself fissions – part of the chain reaction of splitting atoms that is the basis of nuclear power. Any plutonium that does not fission stays in the spent fuel.

How much plutonium is in spent nuclear fuel? ›

Through recycling, up to 96% of the reuseable material in used fuel can be recovered: 1% plutonium, and 95% uranium. The remaining 4% of material are fission products, which are non-recoverable waste.

Do we have enough nuclear fuel? ›

Uranium is a common metal found in rocks and seawater. It occurs naturally in the earth's crust and traces of it are found nearly everywhere. Due to increased mineral exploration, supplies are said to be adequate to meet U.S. energy needs (at current consumption levels) for the next 100 years and perhaps much longer.

How long did it take to make sure element 94 plutonium wasn t any of the other elements through many chemical tests? ›

Within a couple of months element 94 had been conclusively identified and its basic chemistry shown to be like that of uranium. To begin with, the amounts of plutonium produced were invisible to the eye, but by August 1942 there was enough to see and weigh, albeit only 3 millionths of a gram.

Why don't we use plutonium instead of uranium? ›

Neutron shields imply a Plutonium bomb needs an even greater neutron source to trigger the reaction, this means another radioactive core is needed of Beryllium/Polonium. So even though Plutonium is 'easier' to come by than Uranium, its bomb structure requires a lot more engineering and more time to assemble.

Can you use plutonium for nuclear energy? ›

Plutonium has several industrial uses, particularly in the nuclear industry. Plutonium-239 is primarily used as a fuel to power nuclear reactors. In fact, it enters into the composition of MOX fuel – mixed uranium and plutonium oxide.

Who has the biggest stockpile of plutonium? ›

The United Kingdom holds the largest civilian inventory of separated plutonium at 140.6 metric tons.

Which country has the most plutonium? ›

Global Inventory of Separated Plutonium 2021
CountryMilitary Use (ton)Total
Total148538
Russia88.0191.1
US103.187.7
France6.080.8
8 more rows

How much plutonium is left? ›

The global stockpile of separated plutonium was about 560 tons. Of this material, 420 metric tons were produced outside of weapon programs, covered by obligations not to use it in weapons, or not directly suitable for weapons. This leaves about 140 metric tons of plutonium in weapons or available for weapons.

Can we run out of nuclear fuel? ›

The world's present measured resources of uranium (6.1 Mt) in the cost category less than three times present spot prices and used only in conventional reactors, are enough to last for about 90 years. This represents a higher level of assured resources than is normal for most minerals.

How many years will nuclear fuel last? ›

Some will last us about as long as the sun, while others may run out soon and are thus not sustainable. Breeder reactors can power all of humanity for more than 4 billion years. By any reasonable definition, nuclear breeder reactors are indeed renewable.

How much uranium can you legally own? ›

You are allowed to own up to one ton of natural Uranium ore minerals in the United States. There is no limit on activity as long as the samples are naturally occurring minerals.

Will plutonium run out? ›

Even if the Stirling generator is used, plutonium-238 supplies will only stretch through 2022. Any hiccups in funding for plutonium-238 production could put planetary science into a tailspin and delay, strip down, or smother nuclear-powered missions.

How long will it take for plutonium to no longer exist? ›

The longest-lived are plutonium-244, with a half-life of 80.8 million years, plutonium-242, with a half-life of 373,300 years, and plutonium-239, with a half-life of 24,110 years. All of the remaining radioactive isotopes have half-lives that are less than 7,000 years.

How much is the element plutonium worth? ›

Plutonium: Known for its prominent role in nuclear weapons and reactors, both the isotopes- plutonium-239 and plutonium-241 are capable of sustaining a nuclear chain reaction. Despite its high radioactivity and associated dangers, it has a soaring price of minimum of $4,000 per gram.

Why is plutonium preferred for nuclear weapons? ›

Fission. The isotopes uranium-235 and plutonium-239 were selected by the atomic scientists because they readily undergo fission. Fission occurs when a neutron strikes the nucleus of either isotope, splitting the nucleus into fragments and releasing a tremendous amount of energy.

Is plutonium stronger than uranium? ›

Yes, exactly so. While the uranium is fissioning inside the reactor, some neutrons are caught by the non-fissioning isotope of uranium, which is 99% of it. And some small percentage of that converts to plutonium. Plutonium is as fissionable or more fissionable than the uranium isotope that is the useful isotope.

Why is plutonium so special? ›

Both plutonium-239 and plutonium-241 are fissile, meaning that they can sustain a nuclear chain reaction, leading to applications in nuclear weapons and nuclear reactors. Plutonium-240 exhibits a high rate of spontaneous fission, raising the neutron flux of any sample containing it.

Is nuclear waste plutonium? ›

The radioactive waste from spent fuel rods consists primarily of cesium-137 and strontium-90, but it may also include plutonium, which can be considered transuranic waste. The half-lives of these radioactive elements can differ quite extremely.

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